Cyclodextrins: Structure, Properties and Applications

A special issue of Compounds (ISSN 2673-6918).

Deadline for manuscript submissions: closed (31 October 2023) | Viewed by 959

Special Issue Editors


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Department of Physical Chemistry, Faculty of Science, University of Vigo, Ourense, Spain
Interests: physical organic and physical inorganic chemistry; reactivity mechanisms in homogeneous and microheterogeneous media; stability of self-assembly aggregates, and supramolecular chemistry
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Kasetsart Agricultural and Agro-Industrial Product Improvement Institute (KAPI), Kasetsart University, Bangkok, Thailand
Interests: cyclodextrin; encapsulation; bioplastics; films

Special Issue Information

Dear Colleagues,

Cyclodextrins (CD) are cyclic oligomers of α-d-glucopyranose that are obtained through biotechnological processes through bacterial action on starch. What was initially considered a scientific curiosity (its ability to form inclusion complexes with a great diversity of molecules) ended up being shown as the cause of its technological applicability. This means that in the last four decades there has been a progressive increase in scientific publications, review articles and patents directly related to CDs (synthesis, structure, properties, formation of host:guest complexes and applications).

In this Special Issue of Compounds, we intend to compile original scientific articles, communications and bibliographic reviews that deal precisely with cyclodextrins (both as regards their structure, their properties, and their applications).

Prof. Dr. Juan C. Mejuto
Dr. Jaruporn Rakmai
Guest Editors

Manuscript Submission Information

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Keywords

  • cyclodextrins
  • biotechnological processes
  • complexes synthesis
  • structure
  • properties
  • formation

Published Papers (1 paper)

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Research

10 pages, 2339 KiB  
Communication
Alkaline Fading of Malachite Green in β-Cyclodextrins
by Anton Soria-Lopez, Raquel Rodriguez-Fernández and Juan C. Mejuto
Compounds 2024, 4(2), 351-360; https://doi.org/10.3390/compounds4020019 - 13 May 2024
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Abstract
The basic hydrolysis of Malachite Green (MG) in the presence of β-Cyclodextrin (β-CD) has been studied using UV-Vis spectroscopic techniques and at 20 °C. β-CD was found to catalyze the basic hydrolysis. Indeed, this basic hydrolysis is catalyzed by the interaction cyclodextrin hydroxyl [...] Read more.
The basic hydrolysis of Malachite Green (MG) in the presence of β-Cyclodextrin (β-CD) has been studied using UV-Vis spectroscopic techniques and at 20 °C. β-CD was found to catalyze the basic hydrolysis. Indeed, this basic hydrolysis is catalyzed by the interaction cyclodextrin hydroxyl group, in its deprotonated form with the carbocation in the host-guest complex. The proposed model has been successfully applied to a reaction catalyzed by CD. It considers two simultaneous pathways in the aqueous medium involving free hydroxyl ions and the substrate-CD complex. The model allows us to obtain the kinetic parameters including the bimolecular rate constant between MG and HO in bulk water (kw = 1.47 ± 0.01 mol−1s−1), the rate constant between MG and the deprotonated hydroxyl group of β-CD inside the host-guest complex (kCD = 0.25 ± 0.03 s−1) and the binding constant of MG inside the β-CD (KS = 2500 ± 50). This behavior is like the hydrolysis of Cristal Violet (CV) in the same reaction media. Full article
(This article belongs to the Special Issue Cyclodextrins: Structure, Properties and Applications)
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